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Crystalline Silicotitanate Ion Exchange | Alternatives for High …

Outside the SRS program, CST in the form of IE-911 has been incorporated into the Cesium Removal Demonstration Project at ORNL. Approximately 1.2 × 10 5 liters of supernate, obtained from the Melton Valley storage tanks, were processed during the demonstration. Some 265 liters of sorbant were successfully used to remove 1.1 × 10 3 …

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Preliminary Ion Exchange Modeling for Removal of Cesium …

However, the CST material is still being considered as a potential backup ion-exchanger material. The performance of a proposed backup ion-exchange column using IONSIV IE-911 (CST in its engineered-form) material for the removal of cesium from Hanford high level radioactive alkaline waste is discussed.

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Demonstration of Cesium Removal Technologies Using …

U.S. Department of Energy Office of Scientific and Technical Information. Search terms: Advanced search options. ...

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Selective removal of cesium and strontium by crystalline

The cesium K d values varied from 15,000 to 124,000 ml g −1 and Sr K d values varied from 610 to 33,000 ml g −1 during the performance evaluation of 17 inorganic ion exchange materials (pharmacosiderite, sodium zirconium silicate, different forms of CST materials developed by Sandia National Laboratory, zeolite exchangers, etc.) for …

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Design of a Carousel Process for Cesium Removal Using …

Simulation results showed that cesium removal behavior in the pilot-scale test of CCIX experiment, where the column length is 22 ft and the CST is pulsed 1 ft in every 24 hours, was well predicted ...

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Reduced Temperature Cesium Removal from AP-101 Using …

In addition to entrained solids removal from the supernate, the primary goal of TSCR is to remove cesium-137 (137 Cs) by ion exchange, allowing contact handling of the liquid effluent product at the WTP. Crystalline silicotitanate (CST) ion exchange media, manufactured by Honeywell UOP, LLC (product IONSIV™ R9140-B), was selected as …

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Digestion of Crystalline Silicotitanate (CST)

The U.S. Department of Energy's Office of Scientific and Technical Information

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Ion exchange kinetics of cesium for various reaction designs using …

Simulation results showed that cesium removal behavior in the pilot-scale test of CCIX experiment, where the column length is 22 ft and the CST is pulsed 1 ft in every 24 hours, was well predicted by using the values of the effective diffusivities of 1.0 to …

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Cesium ion exchange testing using crystalline silicotitanate …

Crystalline silicotitanate (CST) ion exchange media is planned to be used to remove cesium (137 Cs) from the aqueous phases of the tank wastes. Washington River Protection Solutions requested that Hanford tank waste collected from tank 241-AP-107 be processed using conceived pretreatment steps (suspended solids removal by filtration, Cs …

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TCCR Operational Summary and Optimization for Tank 9 …

Currently at the Savannah River Site (SRS), the Tank Closure Cesium Removal (TCCR) is an "at-tank" process designed to remove cesium from aqueous tank waste. Cesium will be removed by ion exchange using the engineered IONSIV® R9120 form of Crystalline Silicotitanate (CST) media.

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Tank Side Cesium Removal Demonstration Project

Tank side cesium removal system will remove suspended solids and cesium from double-shell tank (DST)liquids to provide LAW feed to the Waste Treatment and Immobilization Plant (WTP) ... •Retains CST media in event of lateral failure •Design Metrics •0.003 inch (75 µm) Screen Slot •< 0.2 psid at 5 gpm •All Welded Construction •Self ...

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Modular Cesium Removal Technology Tank Side Cesium …

Tank Side Cesium Removal (TSCR) Objectives. Demonstrates modular tank-side technology for treating waste supernatant. Filter solids using backwashable filter …

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Modified Isotherm Modeling to Predict Cs Exchange …

Crystalline silicotitanate (CST) can selectively remove cesium (Cs), one of the key high-dose, radioactive components in tank waste, and application has been successfully demonstrated on numerous tank waste supernates and tank waste supernate simulants. Ion exchange using CST has been recently proposed for

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[PDF] Preliminary Ion Exchange Modeling for Removal of Cesium …

However, the CST material is still being considered as a potential backup ion-exchanger material. The performance of a proposed backup ion-exchange column using IONSIV IE-911 (CST in its engineered-form) material for the removal of cesium from Hanford high level radioactive alkaline waste is discussed.

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Ion exchange kinetics of cesium for various reaction designs using …

Simulation results showed that cesium removal behavior in the pilot-scale test of CCIX experiment, where the column length is 22 ft and the CST is pulsed 1 ft in every 24 hours, was well predicted ...

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Designing a commercial ion‐exchange carousel to treat DOE wastes using

A column carousel system was designed to treat nuclear waste at the Savannah River Site. A carousel model was used to simulate cesium removal in an ion-exchange carousel loaded with crystalline silicotitanate (CST) granules. The model accounts for axial dispersion and resistance to film and intraparticle diffusion.

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Reduced Temperature Cesium Removal from AP-101 …

Cesium Removal from AP-101 Using Crystalline Silicotitanate June 2022 AM Westesen EL Campbell AN Williams AM Carney ... (MDL) in the effluent; this was indicative of uptake by the CST. In addition to Cs removal, measurable fractions of calcium (Ca), iron (Fe), strontium (Sr), uranium (U), 237Np, 238Pu, and 239+240Pu also partitioned to the CST ...

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Modular Cesium Removal Technology Tank Side …

Tank Side Cesium Removal (TSCR) Objectives Demonstrates modular tank-side technology for treating waste supernatant Filter solids using backwashable filter technology Remove Cs-137 and Sr-90 with Crystalline Silicotitanate (CST) Early production of feed for WTP LAW-Vitrification commissioning and operation

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The Tank Side Cesium Removal (TSCR) system is currently being constructed to process Hanford tank waste supernates for vitrification. TSCR incorporates a filtration system and cesium (Cs) removal system using columns filled with crystalline silicotitanate (CST) ion exchanger, produced by Honeywell UOP, LLC.

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The Effect of Pressure and Organic Constituents on the Cesium …

The Tank Closure Cesium Removal (TCCR) system uses ion exchange columns filled with Crystalline Silicotitanate (CST) media to process radioactive waste solutions for the removal of Cs137. TCCR currently focuses on dissolving Savannah River Site (SRS) Tank 10H waste (primarily sodium salt cake solids) within the tank followed …

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Designing a commercial ion‐exchange carousel to treat DOE wastes using

Simulation results showed that cesium removal behavior in the pilot-scale test of CCIX experiment, where the column length is 22 ft and the CST is pulsed 1 ft in every 24 hours, was well predicted ...

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Strontium/Strontium‐90 Removal from Chelate‐Bearing

CST was shown to remove cesium from a high‐complexant tank waste, AN‐102 diluted to 5.7 M sodium ions (Na+), comparing well with an existing adsorption isotherm generated with a simplified ...

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Reduced Temperature Cesium Removal from AP-107 …

The Tank Side Cesium Removal (TSCR) system is currently being constructed to process Hanford tank waste supernates for vitrification. TSCR incorporates a filtration system and cesium (Cs) removal system using columns filled with crystalline silicotitanate (CST) ion exchanger, produced by Honeywell UOP, LLC (product IONSIV™ R9140-B).

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Cesium Removal Using CST

Cesium Removal Using Crystalline Silicotitanate Tanks Focus Area DOE/EM-0415. Demonstrated at Hanford Site Richland, Washington and Oak Ridge Reservation ... IE-911 over organic ion-exchange resins for cesium removal. Ionsiv IE-911 is a CST sorbent developed jointly by DOE and industry. Ionsiv IE-911 was initially developed

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Cesium Removal from Simulated SRS High-Level Waste …

Cesium removal in two column tests at rapid feed rates (i.e., supetilcial velocities of 0.98 and 4.1 crn/min) in the range of proposed process conditions closely matched ... previous column experiments examined using CST in SRS wastes. Therefore, Savannah River Technology Center (SRTC) began this study to determine the performance of the

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Cesium removal from high-pH, high-salt wastwater using …

Conference: Cesium removal from high-pH, high-salt wastwater using crystalline silicotitanate sorbent ... crystalline silicotitanate (CST), was chosen on the basis of its effectiveness in laboratory tests. The CST, which was developed through a Cooperative Research and Development Agreement between DOE and private industry, …

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Cesium Removal from 5.5 and 7.0 M Na AP-105 Using …

Crystalline silicotitanate (CST) manufactured by Honeywell UOP, LLC (product IONSIV R9140-B) has been selected as the ion exchange media for TSCR. CST is a non …

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Strontium/strontium‐90 removal from chelate‐bearing …

A study was conducted to evaluate if crystalline silicotitanate (CST) could be used to remove 90 Sr from highly chelated tank waste in support of tank waste immobilization. CST was shown to remove cesium from a high-complexant tank waste, AN-102 diluted to 5.7 M sodium ions (Na +), comparing well with an existing adsorption …

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Preliminary Ion Exchange Modeling for Removal of Cesium …

Crystalline silicotitanate (CST) ion exchanger is planned for use in the removal of cesium (¹³⁷Cs) from the aqueous phase of Hanford tank wastes in preparation for vitrification at the Waste ...

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Cesium Removal from Tank Waste Simulants Using …

This pretreatment will remove cesium from the waste stream using ion exchange (IX). The selected media for IX is crystalline silicotitanate (CST), product …

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CESIUM-137 MEASUREMENTS OF SPENT CST COLUMNS …

Savannah River Remediation (SRR) is currently operating the Tank Closure Cesium Removal (TCCR) process to remove 137 Cs from tank waste supernate using an ion exchange process. As part of that process, Savannah River National Laboratory (SRNL) receives and analyzes samples in support of the qualification of each batch to be …

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Design of a Carousel Process for Removing Cesium from SRS Waste Using

U.S. Department of Energy Office of Scientific and Technical Information. Search terms: Advanced search options. ...

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Development and properties of crystalline silicotitanate (CST…

One particular CST, known as TAM-5, is remarkable for its ability to separate parts-per-million concentrations of cesium from highly alkaline solutions (pH> 14) containing high sodium concentrations (>5M). It is also highly effective for removing cesium from neutral and acidic solutions, and for removing strontium from basic and neutral …

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MODELING CST ION EXCHANGE FOR CESIUM REMOVAL …

The objective of this work is, through modeling, to predict the performance of Crystalline Silicotitinate (CST) for the removal of cesium from Small Column Ion …

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