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Gypsum Crystallization during Phosphoric Acid …

production process are critical to the acid filtration efficiency. In this work, a thermodynamically consistent definition of supersaturation is derived and modeled …

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Preparation of α-High Strength Gypsum from Flue Gas …

The synthesis of α-calcium sulfate hemihydrate (α-CSH) from flue gas desulfurization (FGD) gypsum is a good way to realize the comprehensive utilization of …

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Hemihydrate and Two-Stage Processes

Median hemidihydrate process requirements are given in Table 2. Dihydrate-Hemihydrate Process (DHH) Although the attack and digestion sections are run under dihydrate conditions, it is not desirable to effect a very high degree of P 2 O 5 recovery during the separation of the acid from the dihydrate because the succeeding dehydration …

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Gypsum hemihydrate–cement blends to improve …

The natural gypsum rock reserves are estimated to be about 1.6 billion tons and the gypsum production in 2007 was almost 2 millions tons, and 89% of this production comes from Pernambuco State at Northest region [2]. Availability, the relatively low level of start-up investments, and a favorable market situation, all provide conditions …

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Microstructure and mechanical properties of β-hemihydrate …

1. Introduction. Gypsum (CaSO 4 ·2H 2 O, also known as dihydrate) plaster is one of the earliest building materials elaborated by mankind, and gypsum plasterboard is used widely as indoor building material because of its easy fabrication feature, environmental friendliness, fire resistance, aesthetics, low price, etc. The global …

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New insight into the phase changes of gypsum

Gypsum was also investigated as a partial substitute for ordinary Portland cement. The resulting material is the eco-friendly gypsum-cement composite [].For example, the use of 50% recycled gypsum in cement production could save 6.78 E+07 MJ/year in the non-renewable energy category in Spain alone, and in the global warming …

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Production and resource utilization of flue gas desulfurized gypsum …

Flue gas desulfurized gypsum (FGD gypsum), mainly originates from thermal power plants, smelters, and large-scale enterprise boilers.This article reviews the production in China and the latest beneficial utilizations of FGD gypsum. China is a large coal-consuming country and has always had serious SO 2 emissions. Therefore, the …

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Techno-economic impact assessment of recycled gypsum …

Recycled gypsum derived from post-consumer sources is a promising resource that can be reincorporated in the production chain, offering opportunities to decrease manufacturing costs given its significantly lower price compared to conventional gypsum. The systematic usage of post-consumer recycled gypsum is a relatively new …

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Crystallization kinetics of large-sized columnar α-hemihydrate gypsum …

Direct production of high-strength α-calcium sulfate hemihydrate (α-HH) with no additives was accomplished by the reaction of aluminum sulfate and waste CaCl 2 discarded from Solvay soda plant. For scaling-up this new process, the crystallization kinetics of α-HH was experimentally investigated under varying conditions including …

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Hemihydrate

EM mill, or effective innovative equipment, provides drying, grinding and classifying processes of hemihydrate for further production of gypsum boards. Comparing to …

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Production and resource utilization of flue gas desulfurized …

Flue gas desulfurized gypsum (FGD gypsum), mainly originates from thermal power plants, smelters, and large-scale enterprise boilers. This article reviews the …

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Crystallization Kinetics of α-Hemihydrate Gypsum Prepared …

α-Calcium sulfate hemihydrate (α-HH) is an important cementitious material, which can be prepared by hydrothermal method from calcium sulfate dihydrate (DH) in an electrolyte solution. Study of the conversion kinetics of DH to α-HH in NaCl solution is helpful for understanding the control process. In this paper, X-ray diffraction (XRD) …

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11.16 Gypsum Manufacturing

This research evaluated the influence of several factors in the preparation of hemihydrate gypsum (HH) using concentrated brine and desulfurized gypsum, and …

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Pilot scale preparation of α-calcium sulfate hemihydrate …

1. Introduction. Worldwide, coal continues to be the most important fuel for power generation [1], [2].The application of wet flue gas desulfurization (FGD) project in coal power plants is still increasing to control the exhaust gas due to its high sulfur dioxide removal efficiency, reliability and cost-effectiveness [3].Consequently, large quantity of …

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Preparation of α-calcium sulfate hemihydrate from …

FGD gypsum production and utilization in USA from 2002 to 2018, source-ACAA ... Process., 57(1), 2021, 168-181 PG is generated from the processing of phosphate rock by the "wet acid method" in plants producing phosphoric acid and phosphate fertilizers. ... fertilizer industries. Additionally, anhydrite and hemihydrate gypsum are unstable ...

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Modification on the Performance of the Hemihydrate Gypsum …

The objective of this study was to assess the feasibility of using the plant-source polymer of the matcha powder as a composite admixture for hemihydrate gypsum. Hemihydrate gypsum was mixed with different contents of matcha powder, and then the water requirement for the normal consistency, setting times, density, strength, hydration …

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2 Gypsum dehydration during cement production

The proportions of gypsum, hemihydrate and anhydrite are individually optimized for each type of cement [7]. The dehydration of gypsum to hemihydrate normally takes place during the grinding process in the cement mill. Depending on the mill temperature, the gypsum becomes partially or completely dehydrated to hemihydrate or anhydrite respectively.

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Full Design of Phosphoric Acid Production Plant

Regions indicating precipitated gypsum crystals dihydrate DH, hemihydrate HH, and anhydrategypsum. Regions are defined by temperature of solution and the P2O5% content of the phosphoric acid ...

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Coordinated disposal of FGD gypsum and power plant

The synthesis of hemihydrate gypsum (α-HH) crystals with a low aspect ratio is of great significance to practical production for the effective utilization of flue gas …

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Preparation of gypsum with high purity and whiteness from …

Phosphogypsum (PG) is a solid waste product generated during wet-process phosphoric acid production. Various impurities considerably reduce the purity, whiteness, and application range of PG. This ...

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Utilization of low-quality desulfurized ash from semi-dry …

Desulfurized ash from semi-dry flue gas desulfurization and α-hemihydrate gypsum were collected from Baotian New Building Materials Co.,Ltd. Their chemical components are shown in Table 1.Desulfurized ash contains about 21.33% hemihydrate calcium sulfite, 18.11% calcium carbonate, 28.55% dihydrate gypsum, 25.81% calcium …

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Preparation of α-calcium sulfate hemihydrate from

The synthesis of hemihydrate gypsum (α-HH) crystals with a low aspect ratio is of great significance to practical production for the effective utilization of flue gas desulfurization (FGD) gypsum.

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A comprehensive review of flue gas desulphurized gypsum: …

Flue gas desulfurization (FGD) gypsum is a byproduct of the combustion of coal, used for electricity generation. This material is generated during the process of …

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Fast in-situ X-ray scattering reveals stress sensitivity of gypsum

The dehydration of gypsum to hemihydrate has been studied for decades because it is an important model reaction for understanding fluid-triggered earthquakes, and due to the global use of plaster ...

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Calcium Sulfate Hemihydrate

Metallic, Ceramic and Polymeric Biomaterials. C. Rey, ... D. Grossin, in Comprehensive Biomaterials, 2011 1.111.7.3 CaSO 4-Based Bioactive Ceramics. Calcium sulfate hemihydrate (CaSO 4 ⋅ 1/2H 2 O), known as plaster of Paris, has been used as a building material for at least 5000 years and used by Egyptians to decorate burial tombs of …

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Coordinated disposal of FGD gypsum and power plant

α-hemihydrate (α-HH), known for its exceptional mechanical properties, is a widely used building material. Despite its advantages, the traditional method of producing α-HH through regular pressure brine poses significant drawbacks. These include substantial industrial salt demands, high production costs, and water pollution. A more environmentally friendly α …

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Promotion of conversion activity of flue gas desulfurization …

The poor crystallinity, increased specific surface area, and elimination of organics adsorbed onto crystal surfaces effectively improved the conversion activity of …

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Sustainability of gypsum products as a construction material

Natural gypsum, shown in Fig. 25.1, is the most common raw material for production of binders.It is a soft mineral, attributed to sedimentary rocks, normally grey or with no colour, with a humidity of about 8–10%. Gypseous stone, a denser modification of gypsum that is composed of gypsum and sandy and clayey stone, is normally used to …

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Production and resource utilization of flue gas desulfurized gypsum …

1. Introduction. Flue gas desulfurized gypsum mainly comes from thermal power plants, smelters, and large-enterprise boilers, and contains industrial by-products produced through a wet desulfurization combustion process, where SO 2 gas and lime slurry react under strong oxidation conditions. The main component of this gypsum is …

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Transformation of Flue-Gas-Desulfurization Gypsum to (α …

The synthesis of hemihydrate gypsum (α-HH) crystals with a low aspect ratio is of great significance to practical production for the effective utilization of flue gas desulfurization (FGD) gypsum. In this work, the hexagonal prismatic α-HH crystals with controllable morphology were prepared in Glycerol-NaCl-Water solutions with maleic …

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Enhancing the hydration and micromechanical properties of C3A-gypsum

This study investigates the influence of tannic acid (TA), a natural plant-based biomolecule, on the hydration of tricalcium aluminate (C 3 A)-gypsum systems, aiming to elucidate its potential as a novel concrete strength enhancer. To this end, detailed investigations were conducted into the hydration and nano-mechanical properties of C 3 A-gypsum system …

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(PDF) Production of calcium sulphate alpha-hemihydrate

Gypsum can be produced from natural gypsum rock, but can also be produced from a wide range of industrial by-products, e.g. from the flue gas desulfurization (FGD) of power plants (FGD gypsum) 1 ...

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Coordinated disposal of FGD gypsum and power plant

Direct production of high-strength α-calcium sulfate hemihydrate (α-HH) with no additives was accomplished by the reaction of aluminum sulfate and waste CaCl2 discarded from Solvay soda plant.

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